Key Found to Suppress Thermal Runaway in Batteries

“Prevents EV Fires Like a Fuse”

LG Chem Finds Key to Suppressing Thermal Runaway in Batteries

Press Release: October 2024

□ Developed temperature-responsive material to suppress thermal runaway; Paper published in a leading scientific journal

□ Temperature-responsive material as thin as 1/100 the diameter of a human hair, placed inside the battery cell

□ Acts as a “fuse” to block the reaction path at the early stages of overheating

□ Research paper published in Nature Communications, one of the world’s top scientific journals, in September

■ Lee Jong-gu, CTO, stated:

“This is a tangible research breakthrough that can be applied to mass production in a short period.”

“We will enhance safety technologies so that customers can use electric vehicles with confidence, and further strengthen our competitiveness in the battery market.”

LG Chem Develops New Material to Suppress Thermal Runaway, Preventing Battery Fires at the Early Stage

LG Chem announced on the 1st that its Platform Technology R&D team, under the CTO division, has developed a temperature-responsive Safety Reinforced Layer (SRL), a material designed to suppress thermal runaway. In collaboration with Professor Lee Minah’s team from the Department of Battery Science at POSTECH, the material was analyzed, while the safety verification was conducted in partnership with LG Energy Solution. The research findings were published online in the September edition of Nature Communications, one of the world’s leading scientific journals.

*Paper title: “Thermal Runaway Prevention through Scalable Fabrication of Safety Reinforced Layer in Practical Li-ion Batteries”

The thermal runaway suppression material developed by LG Chem is a composite material that changes its electrical resistance based on temperature, acting as a “fuse” that blocks the flow of electricity in the early stages of overheating.

The research team created this thermal runaway suppression material in the form of a thin layer, just 1 micrometer (1μm) thick—about 1/100th the thickness of a human hair—positioned between the cathode layer and the current collector (an aluminum foil that acts as the electron pathway) in the battery. When the battery’s temperature rises beyond the normal range, between 90°C and 130°C, the material reacts to the heat, altering its molecular structure and effectively suppressing the flow of current.

This thermal runaway suppression material is highly responsive to temperature, with its electrical resistance increasing by 5,000 ohms (Ω) for every 1°C rise in temperature. The material’s maximum resistance is over 1,000 times higher than at normal temperatures, and it also features reversibility, meaning the resistance decreases and returns to its original state, allowing the current to flow normally again once the temperature drops.

Thermal runaway, a leading cause of electric vehicle battery fires, occurs when the cathode and anode inside the battery unintentionally come into direct contact, causing a short circuit and generating heat. Within seconds, the temperature can rise to nearly 1,000°C, leading to a fire. The thermal runaway suppression material is expected to be effective in preventing fires by quickly blocking the reaction path at the early stages of overheating.

In both battery impact and penetration tests, the batteries equipped with the thermal runaway suppression material either did not catch fire at all or extinguished the flames shortly after they appeared, preventing a full-blown thermal runaway event.

In a penetration test involving mobile LCO (Lithium Cobalt Oxide) batteries, where a nail was used to puncture the battery, only 16% of regular batteries did not catch fire. However, none of the batteries with the thermal runaway suppression material experienced any fire incidents.

In an impact test on NCM (Nickel Cobalt Manganese) batteries for electric vehicles, where a 10kg weight was dropped onto the batteries, all of the standard batteries caught fire. In contrast, 70% of the batteries equipped with the thermal runaway suppression material did not ignite at all, while the remaining 30% saw flames, but they were extinguished within seconds.

While previous methods involved placing temperature-responsive materials inside the battery cell, they often faced issues with slow reaction times or reduced energy density. LG Chem, however, has successfully developed a material that resolves such issues, backed by their expertise and patented material design, allowing for rapid application in mass production processes.

LG Chem has completed safety verification tests for the thermal runaway suppression material in mobile batteries and plans to continue safety testing for large-capacity electric vehicle batteries through next year.

Lee Jong-gu, CTO of LG Chem, stated, “This is a tangible research achievement that can be applied to mass production in a short period of time. We will enhance safety technology to ensure customers can use electric vehicles with confidence and contribute to strengthening our competitiveness in the battery market.”

※ Paper Information

• Title: Thermal Runaway Prevention through Scalable Fabrication of Safety Reinforced Layer in Practical Li-ion Batteries

• Lead Author: In-taek Song, Senior Researcher (Professional), LG Chem

• Corresponding Authors: Ki Hwan Kim, Research Fellow, LG Chem; Minah Lee, Professor, POSTECH

• Material Verification and Analysis: POSTECH, LG Energy Solution

Source: LG Chem